BulkStockBll bll = new BulkStockBll();
DataSet ds = bll.GetBulkStock();
this.ddl_BulkStock.DataTextField = "Name" ;
this.ddl_BulkStock.DataValueField = "ID" ;
this.ddl_BulkStock.DataSource = ds;
this.ddl_BulkStock.DataBind();
this.ddl_BulkStock.Items.Add(new ListItem( "全部", "0" ));//第一次選擇！
this.ddl_BulkStock.Items.FindByValue("0" ).Selected = true;
*******************************
this.ddl_BulkStock.Items.FindByValue(infobulkstockid).Selected = true;//第二次選擇！
******************************

<asp:DropDownList ID="Com_Ygrenshu" runat="server" style="margin-left:8px;">
<asp:ListItem Value="0">請選擇人數</asp:ListItem>
<asp:ListItem Selected="True" Value="5">5人以下</asp:ListItem>
<asp:ListItem Value="10">5-10 人</asp:ListItem>
<asp:ListItem Value="50">11-50 人</asp:ListItem>
</asp:DropDownList>

for (int i = 0; i < this.Com_Ygrenshu.Items.Count; i++)
{
Com_Ygrenshu.Items[i].Selected = false;

//如果沒有上面這一句那么將出錯誤:不能在 DropDownList 中選擇多個項
if (Com_Ygrenshu.Items[i].Value.Trim() == ds.Tables[0].Rows[0]["Empl_Num"].ToString().Trim())
{
Com_Ygrenshu.Items[i].Selected = true;
}
}